Anhydrous Ammonia - Refrigeration Grade Safety Data Sheet according to Federal Register / Vol. : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. Section 8: Reformatted and added information for Canada and Mexico, Section 14.1: Updated information for Package Markings and added "Additional Information. Caution: Adding water directly to liquid spills will increase volatilization of ammonia, thus increasing the possibility of exposure. GENERAL: IARC: International Agency for Research on Cancer Anhydrous ammonia is listed under Department of Homeland Security regulation 6 CFR Part 27, Chemical Facility Anti-Terrorism Standards at storage / process amounts greater than the threshold quantity of 10,000 pounds (ammonia, anhydrous). Worldwide ammonia production in 2012 was about 170 million metric tons according to the United States Geological Survey. SPECIAL PRECAUTIONS: "Anhydrous Ammonia" with 2-inch lettering (4 sides). Anhydrous ammonia decomposes to hydrogen and nitrogen gases above 450 °C (842 °F). |*>��҇W��cx?� >��q����a�>�"�;���M����%͞4?�Z�ܦ)��4=1�����5_�a������G� Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. Click a link below for the printer-friendly version of the MSDS. Thaw frozen clothing from skin before removing. If a portable container (such as a cylinder or trailer) can be moved from the fire area without risk to the individual, do so to prevent the pressure relief valve of the trailer or portable container from discharging or the cylinder from rupturing. Anhydrous ammonia SDS Ref. Effects of direct contact may range from irritation and lacrimation to severe injury and blindness. It is the responsibility of the employer to Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc., on affected area. Hans Pasman, in Risk Analysis and Control for Industrial Processes - Gas, Oil and Chemicals, 2015. Exposure Controls / Personal Protection. As a fertilizer, it provides essential nitrogen for plants and is imperative that proper precautions are taken to ensure that it is handled correctly. Product Identifier: Anhydrous Ammonia Last Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet 1. Relevant identified uses : Industrial and professional. Under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA), Section 103, any environmental release of this chemical equal to or over the reportable quantity of 100 pounds must be reported promptly to the National Response Center, Washington, D.C. (1-800-424-8802). Product Name: Ammonia, Anhydrous Anhydrous Ammonia Safety Data Sheet According to Federal Register / Vol. Anhydrous ammonia is transferred and stored as a liquefied, compressed gas and is relatively easy to handle with readily available equipment designed for ammonia service. SPECIAL FIRE FIGHTING PROCEDURES: determine the appropriate hazard classification and personnel protective equipment (PPE) code for this material. If relief valves are inoperative, heat exposed storage containers may become explosion hazards due to over pressurization. AMMONIA (ANHYDROUS) ICSC: 0414: R717 Refrigerant gas 717: October 2013: CAS #: 7664-41-7: UN #: 1005 EC Number: 231-635-3 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Flammable. Decomposition temperatures may be lowered by contact with certain metals, such as iron, nickel and zinc and by catalytic surfaces such as porcelain and pumice. Any party handling, transferring, transporting, storing, applying or otherwise using this product should review thoroughly all applicable laws, rules, regulations, standards and good engineering practices. Mobility in Soil: Anhydrous Ammonia - Refrigeration Grade Safety Data Sheet according to Federal Register / Vol. PEL: Permissible Exposure Limit No smoking No additional information available. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 9 of 12 Issue date: 2015-12-11 Revision 3.0 Print date: 2015-12-11 Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. Section 8. LC50 - 5131 mg/m3 (7338 ppm) to 11,592 mg/m3 (16,600 ppm), 60 minute exposure, Rat. It is either used directly in gas phase reaction or bubbled through the reaction mixture. of page 2) In case of irregular breathing or respiratory arrest provide artificial respiration. 1.3 Ammonia. Recommended use Manufacture of fertilisers, sodium cyanide and explosives. BOC supplies a wide rage of anhydrous ammonia packages from small cylinders for micrographic use through to drums for more industrial applications. Anhydrous ammonia is a highly effective fertilizer that helps farmers feed our growing population and replenish nutrients in the soil. For first aid purposes, at least 5 gallons of clean water in a container designed to provide ready Anhydrous Ammonia Safety Data Sheet Classified according to the UN-GHS as adopted in the US Hazard Communication Standard (HCS 2012), the Canada Hazardous Products Regulations (WHMIS 2015) and Mexico NOM-018-STPS-2000 Revision Date: 10 June 2016 Date of issue: 10 June 2016 Supersedes Date: 2 February 2016 Version:3.0 SECTION 1: IDENTIFICATION Ammonia (Anhydrous) Other names Anhydrous ammonia, ammonia, and ammonia gas. DISPOSAL: Hill Brothers offers refrigeration (premium) grade and commercial grade anhydrous ammonia in bulk tank truck delivery to your facility. SKIN PROTECTION: Ammonia impervious gloves and clothing (such as neoprene, butyl and Teflon) should be worn to prevent contact during normal operations, such as loading/unloading and transfers. Stop source of leak if possible, provided it can be done in a safe manner. Call a doctor/physician and seek medical attention for severe exposure or if symptoms persist. Replaces all previously dated versions. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. CAS: Chemical Abstracts Service select Document Type. Tearing, eye burns, permanent eye damage or blindness may occur. |�}X��O� In the United States, ammonia is primarily used as a feedstock to produce nitrogen fertilizers, such as urea an ammonium sulfate, and is also directly applied to soil as a fertilizer. Not listed in the National Toxicology Program (NTP). Section 1. Contain spill and runoff from entering drains, sewers, streams, lakes and water systems by utilizing methods such as diking, containment, and absorption. ", Section 14.2: Updated "Additional Information" and "Environomental Hazards. Date of issue: 01/01/1981 … : 302 1/17 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Inhalation of vapours may result in pulmonary oedema and chemical pneumonitis. NIOSH: National Institute for Occupational Safety and Health Ammonia, anhydrous Safety Data Sheet P-4562 according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. In case of leaking gas fire: Stop flow of gas before extinguishing. These vessels (gas carriers) are also used to transport liquefied petroleum gas (LPG). Identification Product form : Substance Substance name : Anhydrous Ammonia - Refrigeration Grade IDLH: Immediately Dangerous to Life or Health Gases Under Pressure (Liquefied gas) Composition / Information on Ingredients, CHEMICAL NAME: Ammonia, Anhydrous Rinse continuously with water for several minutes (minimum of 20 minutes). 77, No. Product Identifier: Anhydrous Ammonia Last Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet 1. Company product code 1670. 2672 (AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia) UN Class : 8 (สารกัดกร่อน) See Section 13, Disposal Considerations. Anhydrous means “without water”. comprehensive Hazard Communication Program. Company name CSBP Limited Address State Postcode Kwinana Beach Road, KWINANA Western Australia 6167 Safety Data Sheets (SDS), and employee training. For escape in emergencies, NIOSH approved respiratory protection should be used, such as a full-face gas mask and canisters/cartridges approved for ammonia or SCBA. 1,570 °F (If un-catalyzed). Eyes: HMIS Hazard Index: Synonyms: Ammonia Brief inhalation exposure to 5,000 ppm may be fatal. 1,204 °F (If catalyzed). Select Country. Corporate Emergency Telephone Number: 800-643-6226 Avoid breathing gas/vapors. select. CONDITIONS TO AVOID: To the best of our knowledge, the information, data, and recommendations set forth herein are believed to be accurate. Skin and respiratory related diseases could be aggravated by exposure. Product Name: Anhydrous Ammonia. Anhydrous Ammonia (NH 3) – Ammonia is one of the most widely used inorganic chemicals in the world today. (per 100 pounds of water): 86.9 pounds at 32 °F, 51 pounds at 68 °F. It has also been used for adjusting pH during the synthesis of magnetite-hematite mixture by combustion methods. Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. �{x?| Supportive treatment with necessary ventilation actions, including oxygen, may warrant consideration. employees through training and the use of colors, numbers, letters of the alphabet, and symbols of types of personnel EYE/FACE PROTECTION: Chemical splash goggles should be worn when handling anhydrous ammonia. Anhydrous ammonia is a colorless liquid compressed. Flammable gas. CGA G2.1 - 2014 11.5.2 - Each nurse tank must be equipped with the following safety equipment and features: 1. Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. Will not polymerize. RCRA: Resource Conservation and Recovery Act : 302 5/17 11/20/2012 Emergency procedures : Stop leak if safe to do so. Chemical name :ammonia, anhydrous Supplier's details : Ammonia Product use :Synthetic/Analytical chemistry. Ammonia, anhydrous Safety Data Sheet P-4562 according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Aqua Ammonia Industrial Grade Product Specification For first aid purposes, at least 5 gallons of clean water in a container designed to provide ready 7664-41-7 UN No. For severe vapor contact or if irritation persists, seek medical attention. Suite 400 Northbrook, IL 60062 T 1-800-524-0132 PCS Sales (Canada), Inc. (A Subsidiary of Nutrien) Suite 500 122 1st Avenue South Saskatoon, Saskatchewan Canada S7K 7G3 T 1-800-542-0132 sds@nutrien.com - www.nutrien.com Ammonia, Anhydrous appointment, please call: ° 2016 Tanner Industries, Inc. All Rights Reserved. SCBA: Self Contained Breathing Apparatus Causes severe skin burns and serious eye damage. Ammonia Chemical family Corrosive, caustic, reactive gas Synonyms Anhydrous ammonia, R717 CAS No. Perform risk assessment prior to … Protective equipment should be stored near, but outside of anhydrous ammonia area. ... (See Ammonia Solutions SDS) Advanced treatment: In cases of respiratory compromise secure airway and respiration via endotracheal intubation. Rinse skin with water/shower. Moreover, it should not be assumed that every acceptable test or safety procedure or method, precaution, equipment or device is contained within, or that abnormal or unusual circumstances may not warrant or suggest further requirements or additional procedures. 1005 ERG No. 77, No. Exposure to liquid or rapidly expanding gases may cause severe chemical burns and frostbite to the eyes, lungs and skin. CHEMICAL STABILITY: first aid instructions in Section 4 (First Aid Measures). Anhydrous ammonia has potentially explosive reactions with strong oxidizers. WORKPLACE PROTECTIVE EQUIPMENT: Ammonia Chemical family Corrosive, caustic, reactive gas Synonyms Anhydrous ammonia, R717 CAS No. Aqua Ammonia 14% – 30% SDS. W�-�Н/�q�E�ݸ�R/����,�9�CW�@�b8��7.Z�cm< ���3�veb����z~��e�e+�f8>J�/Y:{I�����FA�%�GA����Q�O� Bٯ�{��3�'�y�'�¯�r_����x>ڎ^C�)������! 58 / Monday, March 26, 2012 / Rules and Regulations 12/13/2017 EN (English US) Page 1 SECTION 1: Identification 1.1. 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